Sustainability footprints of a renewable carbon transition for the petrochemical sector within planetary boundaries

نویسندگان

چکیده

The petrochemical industry requires 25% of Earth’s operating capacitySustainability 50 “renewable” carbon routes for the sector was examinedRoutes with largest CO2 savings transgress biodiversity boundary by 30%Planetary boundaries should be incorporated in decarbonization planning Using novel technologies to curb emissions hard-to-abate industrial sectors has received increasing attention combatting climate change. However, sustainability assessments such are often limited footprint analyses and CO2-emission-saving potential. Here, we assessed impact transitioning away from fossil toward renewable feedstocks relative nine planetary boundaries. We found that decision- policy-making focused solely on mitigating could lead actions severely exacerbate loss compromise resilience. Our results highlight need holistic environmental beyond mitigation potential guide low-carbon transitions underpinning sustainable development. will play a crucial role developing transition technologies, but also contributes significant proportion greenhouse gas emissions. Momentum is building help reduce this sector, particularly through replacing biomass, captured CO2, other recycled resources, broader implications these so-called “solutions” remain unclear. assess overall “renewable pathways” quantifying their life-cycle footprints respect previously defined show although shift pathways indeed over 100%, scenario lowest exceed at least 30%. work highlights pitfalls overlooking global guardrails reduction identifies new avenues solutions sectors. IntroductionThe chemical what known as sector. This footprint, it important providing everyday materials aid stable future.1IPCCGlobal Warming 1.5°C: An IPCC Special Report Impacts Global 1.5°C above Pre-industrial Levels Related Greenhouse Gas Emission Pathways, Context Strengthening Response Threat Climate Change.https://www.ipcc.ch/sr15/Date: 2018Google Scholar It estimated 1.24 Gt CO2-eq annually, accounting about 10% total final energy consumption 7% (GHG) associated industry.2IEA, ICCA, DECHEMATechnology Roadmap Energy GHG Reductions Chemical Industry via Catalytic Processes.https://www.iea.org/reports/technology-roadmap-energy-and-ghg-reductions-in-the-chemical-industry-via-catalytic-processesDate: 2013Google primary source within use obtained primarily resources; sources include those processes indirect Because large majority production chemicals based feedstocks, electrifying or deploying capture storage (CCS) would not fully prevent sector’s strong reliance feedstock.3Schiffer Z.J. Manthiram K. Electrification industry.Joule. 2017; 1: 10-14Abstract Full Text PDF Scopus (161) Google Hence, shifting carbon—i.e., recycling chemicals—has become an appealing strategy emissions, contribute Paris targets,4Bazzanella A.M. Ausfelder F. Low feedstock European industry.https://dechema.de/en/Low_carbon_chemical_industry-path-123212,124930.htmlDate: 2017Google Scholar, 5Kätelhön A. Meys R. Deutz S. Suh Bardow change utilization industry.Proc. Natl. Acad. Sci. USA. 2019; 116: 11187-11194Crossref PubMed (210) 6Boulamanti Moya J.A. efficiency emissions: Prospective scenarios Petrochemical Industry.https://ec.europa.eu/jrc/en/publication/eur-scientific-and-technical-research-reports/energy-efficiency-and-ghg-emissions-prospective-scenarios-chemical-and-petrochemicalDate: 7Gabrielli P. Gazzani M. Mazzotti Role Carbon Capture Utilization, Storage, Biomass Enable Net-Zero-CO2 Emissions Industry.Ind. Eng. Chem. Res. 2020; 59: 7033-7045Crossref (127) and, arguably, improve products.7Gabrielli 8Hepburn C. Adlen E. Beddington J. Carter E.A. Fuss Mac Dowell N. Minx J.C. Smith Williams C.K. technological economic prospects removal.Nature. 575: 87-97Crossref (553) 9Majumdar Deutch Research opportunities negative Gigatonne Scale.Joule. 2018; 2: 805-809Abstract (42) refer approach using carbon” rather than conventional “fossil carbon.”The problematic, because already demand products expected further increase sharply.2IEA, Notably, petrochemicals dominate aspect whole, meaning focus reducing necessary. main blocks industry, which act precursors several fine bulk products, following platform chemicals: ethylene, propylene, benzene, toluene, xylenes, methanol (Figure 1). Ammonia incredibly chemical, considered here does contain carbon. These chemicals, consume around one-third sector2IEA, currently produced (i.e., oil, coal, natural gas) cracking naphtha, ethane, and/or liquefied petroleum (LPG).In recent years, great deal research arisen regarding green approaches manufacture. aforementioned six could, example, generated said approaches, either directly "green" intermediate olefins aromatics, i.e., methanol-to-olefins (MTO) methanol-to-aromatics (MTA) processes. itself biomass resources hydrogenation CO2. In case latter, H2 can water (with vast amounts supplied power sources, e.g., wind, solar, bioenergy CCS [BECCS]5Kätelhön Scholar,10Al-Qahtani González-Garay Bernardi Galán-Martín Á. Pozo Chachuat B. Guillén-Gosálbez G. Electricity grid decarbonisation fuel? A modelling analysis today’s transportation-power nexus.Appl. Energy. 265: 114718Crossref (15) Scholar,11González-Garay Frei M.S. Al-Qahtani Mondelli Pérez-Ramírez Plant-to-planet CO2-based processes.Energy Environ. 12: 3425-3436Crossref Scholar), required point air (via direct [DAC]) then converted into economically valuable various technologies.12Cuéllar-Franca R.M. Azapagic capture, utilisation technologies: critical comparison life cycle impacts.J. Util. 2015; 9: 82-102Crossref (848) Scholar,13Boot-Handford M.E. Abanades Anthony E.J. Blunt M.J. Brandani Fernández J.R. Ferrari M.-C. Gross Hallett J.P. update.Energy 2014; 7: 130-189Crossref Collectively, generally referred (CCU) arguably offer route closed-carbon sector14Styring Quadrelli Armstrong dioxide utilisation: closing cycle. Elsevier, 2014Google 15Otto Grube T. Schiebahn Stolten D. Closing loop: Captured industry.Energy 8: 3283-3297Crossref 16Al-Mamoori Krishnamurthy Rownaghi A.A. Rezaei Technol. 5: 834-849Crossref (265) even deliver balance permanently storing specific plastics construction materials.8Hepburn Furthermore, different types resources—including crops residues—could used provide biogenic conversion biorefinery concept,17de Jong Higson Walsh Wellisch Bio-based value added biorefineries.https://www.ieabioenergy.com/blog/publications/bio-based-chemicals-value-added-products-from-biorefineries/Date: 2012Google potentially achieve neutrality consuming naturally CO2.The entirely clearly offers number new, exciting, some cases beneficial decrease impacts co-benefits reduction.1IPCCGlobal Scholar,18Wesseling J.H. Lechtenböhmer Åhman Nilsson L.J. Worrell Coenen L. intensive processing industries towards deep decarbonization: Characteristics future research.Renew. Sustain. Rev. 79: 1303-1313Crossref (114) 19Sachs J.D. Schmidt-Traub Mazzucato Messner Nakicenovic Rockström Six Transformations Sustainable Development Goals.Nat. 805-814Crossref (477) 20IEAEnergy Technology Perspectives 2017 - Catalysing Transformations. OECD, ScholarHowever, poses challenges. Despite growing interest emerging carbon, largely unexplored due narrow scope current assessments. most studies evaluate single focusing warming (GW) fail consider aspects environment. For Pérez-Fortes et al.21Pérez-Fortes Schöneberger Boulamanti Tzimas Methanol synthesis raw material: Techno-economic assessment.Appl. 2016; 161: 718-732Crossref (426) analyzed net electrolytic H2, whereas Sternberg al.22Sternberg Jens C.M. Life assessment C1-chemicals.Green 19: 2244-2259Crossref quantified C1 chemicals. exhaustive review Cuéllar-Franca Azapagic12Cuéllar-Franca highlighted wider range (LCA) CCU avoid GW only.There only few have sought take more analyze Otto al.15Otto large-scale avoidance 123 routes, considering volume 27 Union states, together selection criteria identify promising pathways. al.23Mac Fennell P.S. Shah Maitland G.C. change.Nat. Clim. Chang. 243-249Crossref (489) present short-term uses 11 concluding alone cope challenge. Similarly, Kätelhön al.5Kätelhön decouple while curbing annual up 3.5 2030. each focuses carbon-emissions potential, has, until now, been threat; hence, they overlook relevant worsen when attempting combat change.That say looked impacts. Meunier al.,24Meunier Chauvy Mouhoubi Thomas De Weireld Alternative CO2.Renew. 146: 1192-1203Crossref (88) production) identified trade-offs between metal/mineral depletion. Recently, Thonemann25Thonemann M.A.N. Environmental production: systematic literature meta-analysis.Appl. 263: 114599Crossref (43) conducted meta-analysis 52 peer-reviewed articles LCA evaluated relation 15 indicators, no one technology performs better across categories production. Gabrielli al.7Gabrielli discussed, qualitatively, (land, material minerals, water) three chains enable carbon-neutral coupled infrastructure, well two routes), highlighting there clear winner among them. Finally, study, related its eight boundaries, but, again, scope.11González-Garay how deployment affect stability Earth is, therefore, still needed.The (PBs) concept provides robust framework decision-making sustainability.26Bjørn Chandrakumar Boulay A.-M. Doka Fang Gondran Hauschild M.Z. Kerkhof King H. Margni al.Review methods absolute applications.Environ. Lett. 15: 083001Crossref (73) PBs define set biophysical limits key Earth-system whose transgression state planet.27Rockström Steffen W. Noone Persson Chapin 3rd, F.S. Lambin E.F. Lenton T.M. Scheffer Folke Schellnhuber H.J. al.A safe space humanity.Nature. 2009; 461: 472-475Crossref (6464) Scholar,28Steffen Richardson Cornell S.E. Fetzer I. Bennett E.M. Biggs Carpenter S.R. de Vries Wit C.A. al.Sustainability. Planetary boundaries: guiding human development changing planet.Science. 347: 1259855Crossref (4797) Quantitative thresholds were jointly (SOS) maximum anthropogenic perturbation, budget shared all activities; context, any PBs’ seriously our well-being.28Steffen 29O’Neill D.W. Fanning A.L. Lamb W.F. Steinberger J.K. good boundaries.Nat. 88-95Crossref (588) 30Lade S.J. Donges J.F. Gerten Hoff Newbold Human amplified system interactions.Nat. : 1-10Google 31Verburg P.H. Dearing Dyke J.G. Van Der Leeuw Seitzinger Syvitski Methods Anthropocene.Glob. Change. 39: 328-340Crossref (187) 32Sterner Barbier E.B. Bateman van den Bijgaart Crépin A.-S. Edenhofer O. Fischer Habla Hassler Johansson-Stenman Policy design Anthropocene.Nat. 14Crossref (109) ScholarHere introduce bottom-up quantifies renewable-carbon lens combines PB characterization framework33Ryberg M.W. Owsianiak methodology linked Boundaries framework.Ecol. Indic. 88: 250-262Crossref (70) ecological method developed Hanafiah al.34Hanafiah M.M. Hendriks A.J. Huijbregts M.A.J. Comparing products.J. Clean. Prod. 2012; 37: 107-114Crossref (25) calculates “holistic” indicator, advance (see experimental procedures).35von der Assen Voll Peters utilization: tutorial review.Chem. Soc. 43: 7982-7994Crossref compares Fossil (the industry’s converting chemicals), taken baseline, alternative rely (details differ presented Note S1 schematic representation shown Figure S1, modeling calculations uncertainty procedures).We find under practices, fossil-based require one-quarter entire capacity planet , which, expected, raises serious concerns sustainability. alleviate trade-offs, routes. allowing highest levels reduction—which storage—exceed threshold 30%, land-use requirements. portfolio PBs, competition sociopolitical barriers hamper transition.ResultsImpacts industryWe start analyzing forecasted 613.6 Mt 2020.2IEA, gas, representing backbone steam naphtha crude oil distillation 24% fuel input industry,36Levi P.G. Cullen J.M. Mapping flows products.Environ. 52: 1725-1734Crossref (106) ammonia omitted responsible 0.91 year−1 (over cycle), 46% embodied top 20 (on basis) 2030 (2.0 year−1).2IEA, Scholar,5Kätelhön terms, attributed represent almost 2% activities,1IPCCGlobal relatively low share (in sectors, transport generation) fails defossilize industry.A picture emerges performance SOS operate sustainably, crossed result 2A). imbalance, atmospheric concentration, ocean acidification, them strongly connected same 24.82%, 25.86%, 8.24%, respectively, allowable level 2B). They followed biosphere integrity (1.89%) negligible contributions (<0.02%), activities, mainly agriculture.32Sterner carrying operate. far exceeds contribution world’s gross domestic product 7.1% 2017,37Oxford EconomicsThe Industry: Catalyzing Growth Addressing World’s Sustainability Challenges.https://www.oxfordeconomics.com/recent-releases/the-global-chemical-industry-catalyzing-growth-and-addressing-our-world-sustainability-challengesDate: 2019Google raising fairness economy. end, equitable distribution open discussion, political decisions perspectives distributive fairness.38Lucas P.L. Wilting H.C. Hof A.F. Vuuren D.P. Allocating economies: Distributional consequences fairness.Glob. 60: 102017Crossref (45) ScholarFigure 2Performance satisfying 2020Show full caption(A) status control variables where axis corresponds level, (SOS = zone depicts SOS, yellow uncertainty, red risk zone. gray region shows part black industry. pressures exerted change, adjusted latest available estimates intactness index (experimental procedures).(B) occupied PB. Boxplots bars indicate variation inventory data whiskers excluding outliers according 1.5 interquartile rule procedures).View Large Image View

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

The Environmental Sustainability of Nations: Benchmarking the Carbon, Water and Land Footprints against Allocated Planetary Boundaries

Growing scientific evidence for the indispensable role of environmental sustainability in sustainable development calls for appropriate frameworks and indicators for environmental sustainability assessment (ESA). In this paper, we operationalize and update the footprint-boundary ESA framework, with a particular focus on its methodological and application extensions to the national level. By usi...

متن کامل

Planetary Boundaries: Ecological Foundations for Sustainability and Management

Management studies on corporate sustainability practices have grown considerably. The field now has significant knowledge of sustainability issues that are firm and industry focused. However, complex ecological problems are increasing, not decreasing. In this paper, we argue that it is time for corporate sustainability scholars to reconsider the ecological and systemic foundations for sustainab...

متن کامل

Sustainability. Planetary boundaries: guiding human development on a changing planet.

The planetary boundaries framework defines a safe operating space for humanity based on the intrinsic biophysical processes that regulate the stability of the Earth system. Here, we revise and update the planetary boundary framework, with a focus on the underpinning biophysical science, based on targeted input from expert research communities and on more general scientific advances over the pas...

متن کامل

Natural Resource Economics, Planetary Boundaries and Strong Sustainability

Earth systems science maintains that there are nine “planetary boundaries” that demarcate a sustainable, safe operating space for humankind for essential global sinks and resources. Respecting these planetary boundaries represents the “strong sustainability” perspective in economics, which argues that some natural capital may not be substituted and are inviolate. In addition, the safe operating...

متن کامل

Strengthening the Link between Life Cycle Assessment and Indicators for Absolute Sustainability To Support Development within Planetary Boundaries.

Indicators for Absolute Sustainability To Support Development within Planetary Boundaries Anders Bjørn,*,† Miriam Diamond,‡ Mikołaj Owsianiak,† Benoît Verzat, and Michael Zwicky Hauschild† †DTU Management Engineering, Quantitative Sustainability Assessment, Technical University of Denmark, Produktionstorvet, Building 424, 2800 Kgs. Lyngby, Denmark ‡Department of Earth Sciences, University Of To...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: One earth

سال: 2021

ISSN: ['2590-3322', '2590-3330']

DOI: https://doi.org/10.1016/j.oneear.2021.04.001